Influence of PbZrO3 doping on the structural and magnetic properties of BiFeO3
Identifieur interne : 000205 ( Russie/Analysis ); précédent : 000204; suivant : 000206Influence of PbZrO3 doping on the structural and magnetic properties of BiFeO3
Auteurs : RBID : Pascal:09-0070149Descripteurs français
- Pascal (Inist)
- Dopage, Propriété magnétique, Solution solide, Réaction état solide, Effet magnétoélectrique, Ferroélectricité, Ferromagnétisme faible, Diffraction RX, Mesure magnétique, Spectrométrie Mössbauer, Champ température, Dépendance température, Effet température, Aimantation, Zirconate de plomb, Oxyde de bismuth, Oxyde de fer, Perovskites, Fer, Antiferromagnétisme, Point Néel, Effet Mössbauer, Ordre magnétique, Etat spin élevé, Site cristallographique, Méthode Rietveld, Diffraction neutron, Diagramme poudre, Structure cristalline, Groupe espace, Diagramme diffraction, Ordre longue distance, Structure magnétique, Addition indium, Diffusion neutron, PbZrO3, BiFeO3, 6110N, 6112L, 6166, 6112E.
- Wicri :
English descriptors
- KwdEn :
- Antiferromagnetism, Bismuth oxide, Crystal structure, Crystallographic site, Diffraction pattern, Doping, Ferroelectricity, High spin states, Indium additions, Iron, Iron oxide, Lead zirconates, Long-range order, Magnetic measurement, Magnetic ordering, Magnetic properties, Magnetic structure, Magnetization, Magnetoelectric effects, Moessbauer effect, Moessbauer spectroscopy, Neel temperature, Neutron diffraction, Neutron diffusion, Perovskites, Powder pattern, Rietveld method, Solid solutions, Solid state reaction, Space groups, Temperature dependence, Temperature distribution, Temperature effects, Weak ferromagnetism, XRD.
Abstract
Solid solutions of the perovskites (1 - x)BiFe03-xPbZrO3 with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe03-xPbZr03 samples showed antiferromagnetic behavior with Neel temperatures, TN= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at TN in both samples reaching about 0.01 μB/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe3+ cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below TN with a G-type antiferromagnetic arrangement of the magnetic moments of Fe3+ cations in the B-site. The effect of PbZrO3 doping on BiFe03 results in a noticeable lattice expansion and a significant decrease of TN. The factors governing the observed structural and magnetic properties of (1 - x)BiFe03-xPbZrO3are discussed and compared with those of pure BiFe03.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Influence of PbZrO<sub>3</sub>
doping on the structural and magnetic properties of BiFeO<sub>3</sub>
</title>
<author><name sortKey="Ivanov, S A" uniqKey="Ivanov S">S. A. Ivanov</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Department of Inorganic Materials, Karpov Institute of Physical Chemistry</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
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<country>Russie</country>
<placeName><settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Materials Chemistry, The Angstrom Laboratory, University of Uppsala, Box 538</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Suède</country>
<wicri:noRegion>751 21 Uppsala</wicri:noRegion>
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<author><name sortKey="Nordblad, P" uniqKey="Nordblad P">P. Nordblad</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Engineering Sciences, The Angstrom Laboratory, University of Uppsala, Box 534</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Suède</country>
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</author>
<author><name sortKey="Tellgren, R" uniqKey="Tellgren R">R. Tellgren</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Materials Chemistry, The Angstrom Laboratory, University of Uppsala, Box 538</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Suède</country>
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<author><name sortKey="Ericsson, T" uniqKey="Ericsson T">T. Ericsson</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Physics, University of Uppsala, Box 530</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Suède</country>
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<author><name sortKey="Korchagina, S K" uniqKey="Korchagina S">S. K. Korchagina</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Department of Inorganic Materials, Karpov Institute of Physical Chemistry</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
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<region>District fédéral central</region>
</placeName>
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<author><name sortKey="Rybakova, L F" uniqKey="Rybakova L">L. F. Rybakova</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Department of Inorganic Materials, Karpov Institute of Physical Chemistry</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
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<country>Russie</country>
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<region>District fédéral central</region>
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<author><name sortKey="Hewat, A" uniqKey="Hewat A">A. Hewat</name>
<affiliation wicri:level="1"><inist:fA14 i1="05"><s1>institute Laue-Langevin</s1>
<s2>Grenoble</s2>
<s3>FRA</s3>
<sZ>7 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="région">Rhône-Alpes</region>
<settlement type="city">Grenoble</settlement>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">09-0070149</idno>
<date when="2008">2008</date>
<idno type="stanalyst">PASCAL 09-0070149 INIST</idno>
<idno type="RBID">Pascal:09-0070149</idno>
<idno type="wicri:Area/Main/Corpus">005C73</idno>
<idno type="wicri:Area/Main/Repository">006464</idno>
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</publicationStmt>
<seriesStmt><idno type="ISSN">1293-2558</idno>
<title level="j" type="abbreviated">Solid state sci.</title>
<title level="j" type="main">Solid state sciences</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term>
<term>Bismuth oxide</term>
<term>Crystal structure</term>
<term>Crystallographic site</term>
<term>Diffraction pattern</term>
<term>Doping</term>
<term>Ferroelectricity</term>
<term>High spin states</term>
<term>Indium additions</term>
<term>Iron</term>
<term>Iron oxide</term>
<term>Lead zirconates</term>
<term>Long-range order</term>
<term>Magnetic measurement</term>
<term>Magnetic ordering</term>
<term>Magnetic properties</term>
<term>Magnetic structure</term>
<term>Magnetization</term>
<term>Magnetoelectric effects</term>
<term>Moessbauer effect</term>
<term>Moessbauer spectroscopy</term>
<term>Neel temperature</term>
<term>Neutron diffraction</term>
<term>Neutron diffusion</term>
<term>Perovskites</term>
<term>Powder pattern</term>
<term>Rietveld method</term>
<term>Solid solutions</term>
<term>Solid state reaction</term>
<term>Space groups</term>
<term>Temperature dependence</term>
<term>Temperature distribution</term>
<term>Temperature effects</term>
<term>Weak ferromagnetism</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Dopage</term>
<term>Propriété magnétique</term>
<term>Solution solide</term>
<term>Réaction état solide</term>
<term>Effet magnétoélectrique</term>
<term>Ferroélectricité</term>
<term>Ferromagnétisme faible</term>
<term>Diffraction RX</term>
<term>Mesure magnétique</term>
<term>Spectrométrie Mössbauer</term>
<term>Champ température</term>
<term>Dépendance température</term>
<term>Effet température</term>
<term>Aimantation</term>
<term>Zirconate de plomb</term>
<term>Oxyde de bismuth</term>
<term>Oxyde de fer</term>
<term>Perovskites</term>
<term>Fer</term>
<term>Antiferromagnétisme</term>
<term>Point Néel</term>
<term>Effet Mössbauer</term>
<term>Ordre magnétique</term>
<term>Etat spin élevé</term>
<term>Site cristallographique</term>
<term>Méthode Rietveld</term>
<term>Diffraction neutron</term>
<term>Diagramme poudre</term>
<term>Structure cristalline</term>
<term>Groupe espace</term>
<term>Diagramme diffraction</term>
<term>Ordre longue distance</term>
<term>Structure magnétique</term>
<term>Addition indium</term>
<term>Diffusion neutron</term>
<term>PbZrO3</term>
<term>BiFeO3</term>
<term>6110N</term>
<term>6112L</term>
<term>6166</term>
<term>6112E</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Dopage</term>
<term>Fer</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Solid solutions of the perovskites (1 - x)BiFe0<sub>3</sub>
-xPbZrO<sub>3</sub>
with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe0<sub>3</sub>
-xPbZr0<sub>3</sub>
samples showed antiferromagnetic behavior with Neel temperatures, T<sub>N</sub>
= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at T<sub>N</sub>
in both samples reaching about 0.01 <sub>μB</sub>
/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe<sup>3+</sup>
cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below T<sub>N</sub>
with a G-type antiferromagnetic arrangement of the magnetic moments of Fe<sup>3+</sup>
cations in the B-site. The effect of PbZrO<sub>3</sub>
doping on BiFe0<sub>3</sub>
results in a noticeable lattice expansion and a significant decrease of T<sub>N</sub>
. The factors governing the observed structural and magnetic properties of (1 - x)BiFe0<sub>3</sub>
-xPbZrO<sub>3</sub>
are discussed and compared with those of pure BiFe0<sub>3</sub>
.</div>
</front>
</TEI>
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<fA08 i1="01" i2="1" l="ENG"><s1>Influence of PbZrO<sub>3</sub>
doping on the structural and magnetic properties of BiFeO<sub>3</sub>
</s1>
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<fA11 i1="01" i2="1"><s1>IVANOV (S. A.)</s1>
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<fA11 i1="02" i2="1"><s1>NORDBLAD (P.)</s1>
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<fA11 i1="03" i2="1"><s1>TELLGREN (R.)</s1>
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<fA11 i1="04" i2="1"><s1>ERICSSON (T.)</s1>
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</fA11>
<fA11 i1="07" i2="1"><s1>HEWAT (A.)</s1>
</fA11>
<fA14 i1="01"><s1>Department of Inorganic Materials, Karpov Institute of Physical Chemistry</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Department of Materials Chemistry, The Angstrom Laboratory, University of Uppsala, Box 538</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Department of Engineering Sciences, The Angstrom Laboratory, University of Uppsala, Box 534</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>Department of Physics, University of Uppsala, Box 530</s1>
<s2>751 21 Uppsala</s2>
<s3>SWE</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="05"><s1>institute Laue-Langevin</s1>
<s2>Grenoble</s2>
<s3>FRA</s3>
<sZ>7 aut.</sZ>
</fA14>
<fA20><s1>1875-1885</s1>
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<fA23 i1="01"><s0>ENG</s0>
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<fA45><s0>61 ref.</s0>
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<fA47 i1="01" i2="1"><s0>09-0070149</s0>
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<fA60><s1>P</s1>
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<fA66 i1="01"><s0>FRA</s0>
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<fC01 i1="01" l="ENG"><s0>Solid solutions of the perovskites (1 - x)BiFe0<sub>3</sub>
-xPbZrO<sub>3</sub>
with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe0<sub>3</sub>
-xPbZr0<sub>3</sub>
samples showed antiferromagnetic behavior with Neel temperatures, T<sub>N</sub>
= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at T<sub>N</sub>
in both samples reaching about 0.01 <sub>μB</sub>
/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe<sup>3+</sup>
cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below T<sub>N</sub>
with a G-type antiferromagnetic arrangement of the magnetic moments of Fe<sup>3+</sup>
cations in the B-site. The effect of PbZrO<sub>3</sub>
doping on BiFe0<sub>3</sub>
results in a noticeable lattice expansion and a significant decrease of T<sub>N</sub>
. The factors governing the observed structural and magnetic properties of (1 - x)BiFe0<sub>3</sub>
-xPbZrO<sub>3</sub>
are discussed and compared with those of pure BiFe0<sub>3</sub>
.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A10N</s0>
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<fC02 i1="03" i2="3"><s0>001B60A66</s0>
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<fC02 i1="04" i2="3"><s0>001B60A12E</s0>
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<fC03 i1="01" i2="X" l="FRE"><s0>Dopage</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Doping</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Doping</s0>
<s5>01</s5>
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<fC03 i1="02" i2="3" l="FRE"><s0>Propriété magnétique</s0>
<s5>02</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Magnetic properties</s0>
<s5>02</s5>
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<fC03 i1="03" i2="3" l="FRE"><s0>Solution solide</s0>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="ENG"><s0>Solid solutions</s0>
<s5>03</s5>
</fC03>
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<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Solid state reaction</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Reacción estado sólido</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Effet magnétoélectrique</s0>
<s5>05</s5>
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<fC03 i1="05" i2="3" l="ENG"><s0>Magnetoelectric effects</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Ferroélectricité</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Ferroelectricity</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Ferromagnétisme faible</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Weak ferromagnetism</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>XRD</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Mesure magnétique</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Magnetic measurement</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Medida magnética</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Spectrométrie Mössbauer</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Moessbauer spectroscopy</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Champ température</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Temperature distribution</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Dépendance température</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Temperature dependence</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Effet température</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Temperature effects</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Aimantation</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Magnetization</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Zirconate de plomb</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Lead zirconates</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Oxyde de bismuth</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Bismuth oxide</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Bismuto óxido</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Oxyde de fer</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Iron oxide</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Hierro óxido</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>Perovskites</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG"><s0>Perovskites</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Fer</s0>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="3" l="ENG"><s0>Iron</s0>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Antiferromagnétisme</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="3" l="ENG"><s0>Antiferromagnetism</s0>
<s5>29</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Point Néel</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="3" l="ENG"><s0>Neel temperature</s0>
<s5>30</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE"><s0>Effet Mössbauer</s0>
<s5>31</s5>
</fC03>
<fC03 i1="22" i2="3" l="ENG"><s0>Moessbauer effect</s0>
<s5>31</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE"><s0>Ordre magnétique</s0>
<s5>32</s5>
</fC03>
<fC03 i1="23" i2="3" l="ENG"><s0>Magnetic ordering</s0>
<s5>32</s5>
</fC03>
<fC03 i1="24" i2="3" l="FRE"><s0>Etat spin élevé</s0>
<s5>33</s5>
</fC03>
<fC03 i1="24" i2="3" l="ENG"><s0>High spin states</s0>
<s5>33</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE"><s0>Site cristallographique</s0>
<s5>34</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG"><s0>Crystallographic site</s0>
<s5>34</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA"><s0>Sitio cristalográfico</s0>
<s5>34</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE"><s0>Méthode Rietveld</s0>
<s5>35</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG"><s0>Rietveld method</s0>
<s5>35</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA"><s0>Método Rietveld</s0>
<s5>35</s5>
</fC03>
<fC03 i1="27" i2="3" l="FRE"><s0>Diffraction neutron</s0>
<s5>36</s5>
</fC03>
<fC03 i1="27" i2="3" l="ENG"><s0>Neutron diffraction</s0>
<s5>36</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE"><s0>Diagramme poudre</s0>
<s5>37</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG"><s0>Powder pattern</s0>
<s5>37</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA"><s0>Diagrama polvo</s0>
<s5>37</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>38</s5>
</fC03>
<fC03 i1="29" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>38</s5>
</fC03>
<fC03 i1="30" i2="3" l="FRE"><s0>Groupe espace</s0>
<s5>39</s5>
</fC03>
<fC03 i1="30" i2="3" l="ENG"><s0>Space groups</s0>
<s5>39</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE"><s0>Diagramme diffraction</s0>
<s5>40</s5>
</fC03>
<fC03 i1="31" i2="X" l="ENG"><s0>Diffraction pattern</s0>
<s5>40</s5>
</fC03>
<fC03 i1="31" i2="X" l="SPA"><s0>Diagrama difracción</s0>
<s5>40</s5>
</fC03>
<fC03 i1="32" i2="3" l="FRE"><s0>Ordre longue distance</s0>
<s5>41</s5>
</fC03>
<fC03 i1="32" i2="3" l="ENG"><s0>Long-range order</s0>
<s5>41</s5>
</fC03>
<fC03 i1="33" i2="3" l="FRE"><s0>Structure magnétique</s0>
<s5>42</s5>
</fC03>
<fC03 i1="33" i2="3" l="ENG"><s0>Magnetic structure</s0>
<s5>42</s5>
</fC03>
<fC03 i1="34" i2="3" l="FRE"><s0>Addition indium</s0>
<s5>43</s5>
</fC03>
<fC03 i1="34" i2="3" l="ENG"><s0>Indium additions</s0>
<s5>43</s5>
</fC03>
<fC03 i1="35" i2="3" l="FRE"><s0>Diffusion neutron</s0>
<s5>44</s5>
</fC03>
<fC03 i1="35" i2="3" l="ENG"><s0>Neutron diffusion</s0>
<s5>44</s5>
</fC03>
<fC03 i1="36" i2="3" l="FRE"><s0>PbZrO3</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="37" i2="3" l="FRE"><s0>BiFeO3</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="38" i2="3" l="FRE"><s0>6110N</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="39" i2="3" l="FRE"><s0>6112L</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="40" i2="3" l="FRE"><s0>6166</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fC03 i1="41" i2="3" l="FRE"><s0>6112E</s0>
<s4>INC</s4>
<s5>74</s5>
</fC03>
<fN21><s1>054</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>
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