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Influence of PbZrO3 doping on the structural and magnetic properties of BiFeO3

Identifieur interne : 000205 ( Russie/Analysis ); précédent : 000204; suivant : 000206

Influence of PbZrO3 doping on the structural and magnetic properties of BiFeO3

Auteurs : RBID : Pascal:09-0070149

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English descriptors

Abstract

Solid solutions of the perovskites (1 - x)BiFe03-xPbZrO3 with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe03-xPbZr03 samples showed antiferromagnetic behavior with Neel temperatures, TN= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at TN in both samples reaching about 0.01 μB/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe3+ cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below TN with a G-type antiferromagnetic arrangement of the magnetic moments of Fe3+ cations in the B-site. The effect of PbZrO3 doping on BiFe03 results in a noticeable lattice expansion and a significant decrease of TN. The factors governing the observed structural and magnetic properties of (1 - x)BiFe03-xPbZrO3are discussed and compared with those of pure BiFe03.

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Pascal:09-0070149

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<title xml:lang="en" level="a">Influence of PbZrO
<sub>3</sub>
doping on the structural and magnetic properties of BiFeO
<sub>3</sub>
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<name sortKey="Ivanov, S A" uniqKey="Ivanov S">S. A. Ivanov</name>
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<s1>Department of Inorganic Materials, Karpov Institute of Physical Chemistry</s1>
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<s1>Department of Materials Chemistry, The Angstrom Laboratory, University of Uppsala, Box 538</s1>
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<term>Antiferromagnetism</term>
<term>Bismuth oxide</term>
<term>Crystal structure</term>
<term>Crystallographic site</term>
<term>Diffraction pattern</term>
<term>Doping</term>
<term>Ferroelectricity</term>
<term>High spin states</term>
<term>Indium additions</term>
<term>Iron</term>
<term>Iron oxide</term>
<term>Lead zirconates</term>
<term>Long-range order</term>
<term>Magnetic measurement</term>
<term>Magnetic ordering</term>
<term>Magnetic properties</term>
<term>Magnetic structure</term>
<term>Magnetization</term>
<term>Magnetoelectric effects</term>
<term>Moessbauer effect</term>
<term>Moessbauer spectroscopy</term>
<term>Neel temperature</term>
<term>Neutron diffraction</term>
<term>Neutron diffusion</term>
<term>Perovskites</term>
<term>Powder pattern</term>
<term>Rietveld method</term>
<term>Solid solutions</term>
<term>Solid state reaction</term>
<term>Space groups</term>
<term>Temperature dependence</term>
<term>Temperature distribution</term>
<term>Temperature effects</term>
<term>Weak ferromagnetism</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Dopage</term>
<term>Propriété magnétique</term>
<term>Solution solide</term>
<term>Réaction état solide</term>
<term>Effet magnétoélectrique</term>
<term>Ferroélectricité</term>
<term>Ferromagnétisme faible</term>
<term>Diffraction RX</term>
<term>Mesure magnétique</term>
<term>Spectrométrie Mössbauer</term>
<term>Champ température</term>
<term>Dépendance température</term>
<term>Effet température</term>
<term>Aimantation</term>
<term>Zirconate de plomb</term>
<term>Oxyde de bismuth</term>
<term>Oxyde de fer</term>
<term>Perovskites</term>
<term>Fer</term>
<term>Antiferromagnétisme</term>
<term>Point Néel</term>
<term>Effet Mössbauer</term>
<term>Ordre magnétique</term>
<term>Etat spin élevé</term>
<term>Site cristallographique</term>
<term>Méthode Rietveld</term>
<term>Diffraction neutron</term>
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<term>Groupe espace</term>
<term>Diagramme diffraction</term>
<term>Ordre longue distance</term>
<term>Structure magnétique</term>
<term>Addition indium</term>
<term>Diffusion neutron</term>
<term>PbZrO3</term>
<term>BiFeO3</term>
<term>6110N</term>
<term>6112L</term>
<term>6166</term>
<term>6112E</term>
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<term>Dopage</term>
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<div type="abstract" xml:lang="en">Solid solutions of the perovskites (1 - x)BiFe0
<sub>3</sub>
-xPbZrO
<sub>3</sub>
with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe0
<sub>3</sub>
-xPbZr0
<sub>3</sub>
samples showed antiferromagnetic behavior with Neel temperatures, T
<sub>N</sub>
= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at T
<sub>N</sub>
in both samples reaching about 0.01
<sub>μB</sub>
/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe
<sup>3+</sup>
cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below T
<sub>N</sub>
with a G-type antiferromagnetic arrangement of the magnetic moments of Fe
<sup>3+</sup>
cations in the B-site. The effect of PbZrO
<sub>3</sub>
doping on BiFe0
<sub>3</sub>
results in a noticeable lattice expansion and a significant decrease of T
<sub>N</sub>
. The factors governing the observed structural and magnetic properties of (1 - x)BiFe0
<sub>3</sub>
-xPbZrO
<sub>3</sub>
are discussed and compared with those of pure BiFe0
<sub>3</sub>
.</div>
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<s0>Solid solutions of the perovskites (1 - x)BiFe0
<sub>3</sub>
-xPbZrO
<sub>3</sub>
with x ranging from 0 to 0.2 were synthesized by solid-state reaction in an attempt to find magnetoelectric materials, in which ferroelectricity and ferromagnetism coexist. These complex perovskites have been studied by X-ray and neutron powder diffractions, magnetic and Mössbauer spectroscopic measurements. All samples are single phase with rhombohedrally distorted perovskite structure. The field and temperature dependences of the magnetization of (1 - x)BiFe0
<sub>3</sub>
-xPbZr0
<sub>3</sub>
samples showed antiferromagnetic behavior with Neel temperatures, T
<sub>N</sub>
= 635 K (x = 0.1) and 500 K (x = 0.2); a weak ferromagnetic moment appeared at T
<sub>N</sub>
in both samples reaching about 0.01
<sub>μB</sub>
/Fe at low temperature for the x = 0.1 sample. Mössbauer spectra also support the existence of the magnetic order and are consistent with the presence of high-spin Fe
<sup>3+</sup>
cations located in the octahedral B-site position. Rietveld refinements of neutron powder diffraction data collected at different temperatures, between 10 and 700 K, have been carried out. The structure of these compounds is a rhombohedrally distorted perovskite (space group R3c) within the whole temperature interval. The Bi/Pb and Fe/Zr ions were found to be disordered over the perovskite A- and B-sites, respectively. Neutron diffraction patterns showed evidence of a long-range magnetic ordering below T
<sub>N</sub>
with a G-type antiferromagnetic arrangement of the magnetic moments of Fe
<sup>3+</sup>
cations in the B-site. The effect of PbZrO
<sub>3</sub>
doping on BiFe0
<sub>3</sub>
results in a noticeable lattice expansion and a significant decrease of T
<sub>N</sub>
. The factors governing the observed structural and magnetic properties of (1 - x)BiFe0
<sub>3</sub>
-xPbZrO
<sub>3</sub>
are discussed and compared with those of pure BiFe0
<sub>3</sub>
.</s0>
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<s5>01</s5>
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<s0>Doping</s0>
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<s5>05</s5>
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<s5>06</s5>
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<s5>10</s5>
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<s0>Moessbauer spectroscopy</s0>
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<s0>Temperature distribution</s0>
<s5>11</s5>
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<s0>Dépendance température</s0>
<s5>12</s5>
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<s0>Temperature dependence</s0>
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<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Bismuto óxido</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Oxyde de fer</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Iron oxide</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Hierro óxido</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Perovskites</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Perovskites</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>Fer</s0>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="3" l="ENG">
<s0>Iron</s0>
<s2>NC</s2>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>Antiferromagnétisme</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="3" l="ENG">
<s0>Antiferromagnetism</s0>
<s5>29</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE">
<s0>Point Néel</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="3" l="ENG">
<s0>Neel temperature</s0>
<s5>30</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE">
<s0>Effet Mössbauer</s0>
<s5>31</s5>
</fC03>
<fC03 i1="22" i2="3" l="ENG">
<s0>Moessbauer effect</s0>
<s5>31</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE">
<s0>Ordre magnétique</s0>
<s5>32</s5>
</fC03>
<fC03 i1="23" i2="3" l="ENG">
<s0>Magnetic ordering</s0>
<s5>32</s5>
</fC03>
<fC03 i1="24" i2="3" l="FRE">
<s0>Etat spin élevé</s0>
<s5>33</s5>
</fC03>
<fC03 i1="24" i2="3" l="ENG">
<s0>High spin states</s0>
<s5>33</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>Site cristallographique</s0>
<s5>34</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG">
<s0>Crystallographic site</s0>
<s5>34</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA">
<s0>Sitio cristalográfico</s0>
<s5>34</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE">
<s0>Méthode Rietveld</s0>
<s5>35</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG">
<s0>Rietveld method</s0>
<s5>35</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA">
<s0>Método Rietveld</s0>
<s5>35</s5>
</fC03>
<fC03 i1="27" i2="3" l="FRE">
<s0>Diffraction neutron</s0>
<s5>36</s5>
</fC03>
<fC03 i1="27" i2="3" l="ENG">
<s0>Neutron diffraction</s0>
<s5>36</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE">
<s0>Diagramme poudre</s0>
<s5>37</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG">
<s0>Powder pattern</s0>
<s5>37</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA">
<s0>Diagrama polvo</s0>
<s5>37</s5>
</fC03>
<fC03 i1="29" i2="3" l="FRE">
<s0>Structure cristalline</s0>
<s5>38</s5>
</fC03>
<fC03 i1="29" i2="3" l="ENG">
<s0>Crystal structure</s0>
<s5>38</s5>
</fC03>
<fC03 i1="30" i2="3" l="FRE">
<s0>Groupe espace</s0>
<s5>39</s5>
</fC03>
<fC03 i1="30" i2="3" l="ENG">
<s0>Space groups</s0>
<s5>39</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE">
<s0>Diagramme diffraction</s0>
<s5>40</s5>
</fC03>
<fC03 i1="31" i2="X" l="ENG">
<s0>Diffraction pattern</s0>
<s5>40</s5>
</fC03>
<fC03 i1="31" i2="X" l="SPA">
<s0>Diagrama difracción</s0>
<s5>40</s5>
</fC03>
<fC03 i1="32" i2="3" l="FRE">
<s0>Ordre longue distance</s0>
<s5>41</s5>
</fC03>
<fC03 i1="32" i2="3" l="ENG">
<s0>Long-range order</s0>
<s5>41</s5>
</fC03>
<fC03 i1="33" i2="3" l="FRE">
<s0>Structure magnétique</s0>
<s5>42</s5>
</fC03>
<fC03 i1="33" i2="3" l="ENG">
<s0>Magnetic structure</s0>
<s5>42</s5>
</fC03>
<fC03 i1="34" i2="3" l="FRE">
<s0>Addition indium</s0>
<s5>43</s5>
</fC03>
<fC03 i1="34" i2="3" l="ENG">
<s0>Indium additions</s0>
<s5>43</s5>
</fC03>
<fC03 i1="35" i2="3" l="FRE">
<s0>Diffusion neutron</s0>
<s5>44</s5>
</fC03>
<fC03 i1="35" i2="3" l="ENG">
<s0>Neutron diffusion</s0>
<s5>44</s5>
</fC03>
<fC03 i1="36" i2="3" l="FRE">
<s0>PbZrO3</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="37" i2="3" l="FRE">
<s0>BiFeO3</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="38" i2="3" l="FRE">
<s0>6110N</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="39" i2="3" l="FRE">
<s0>6112L</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="40" i2="3" l="FRE">
<s0>6166</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fC03 i1="41" i2="3" l="FRE">
<s0>6112E</s0>
<s4>INC</s4>
<s5>74</s5>
</fC03>
<fN21>
<s1>054</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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